2024      2023     2022     2021     2020     2019     2018      2017     2016     2015     2014

 2013     2012     2011     2010      2009     2008   

 

2024年发表论文

(226) Li, Y.;# Mou, L.-H.;# Jiang, G.-D.; Li, Z.-Y.; *He, S.-G.; *Chen, H. Toward Designing Reactive Metal Clusters for Dinitrogen Activation: A Guideline Based on N2 Initial Adsorption, Ingor. Chem. 2024, 63, 10775-10785.

(225) Sun, C.-M.; Wei, G.-P.; *Yang, Y.; *Zhao, Y.-X. Thermal Reaction of NiAl₃O₆⁺ and Al₄O₆⁺ with Methane: Reactivity Enhanced by Doping, J. Phys. Chem. A 2024, 128, 1218-1225.

(224) Zhao, X.-G.,# *Zhao, Y.-X.,# *He, S.-G. Reactivity of Atomic Oxygen Radical Anions on Metal Oxide Clusters, ChemPlusChem 2024, in revision.

(223) Zhou, H.; Ruan, M.; Liu, Q.-Y.; Zhao, Y.-X.;Wang, R.-Y.; *Yang, Y.; *He, S.-G. Size-Dependent Reactivity of V_nO⁺ (n =1-9) Clusters with Ethane. Phys. Chem. Chem. Phys. 2024, 26, 14186.

(222) Hu, Y.-Z.; Wei, G.-P.; Zhao, Y.-X.; Liu, Q.-Y.; *He, S.-G. Experimental Reactivity of (MoO₃)_NO⁻ (N = 1–21) Cluster Anions with C₁-C₄ Alkanes: A Simple Model to Predict the Reactivity with Methane. J. Phys. Chem. A 2024, 128, 5253-5259.

(221) Zhao, A.; Liu, Qing.-Y.; Li, Z.-Y.; *Li, X.-N.; *He, S.-G. Reverse Water-Gas Shift Catalyzed by Rh_nVO_3,4^-(n = 3-7) Cluster Anions under Variable Temperatures.  Dalton T. 2024, 53, 8347-8355.

(220) Li, Q.; *Liu, Q.-Y.; *Zhao, Y.-X.; He, S.-G. Conversion of Methane at Room Temperature Mediated by the Ta-Ta σ-Bond. JACS Au 2024, 4, 1824-1832.

(219) Zhao, X.-G.;# Yang, Q.;# Xu, Y.; Liu, Q.-Y.; Li, Z.-Y.; Liu, X.-X.; *Zhao, Y.-X.; *He, S.-G. Machine Learning for Experimental Reactivity of a Set of Metal Clusters toward C-H Activation. J. Am. Chem. Soc.  2024, 146, 12485-12495.

(218) Yang, Q.; Li, Z.-Y.; Rodríguez-Kessler, Peter; *He, S.-G. Accelerated Global Optimization via the Deep Neural Network Complemented with Transfer Learning and Genetic Algorithm. Chinese J. Chem. Phys. 2024, 37, 321-329.

(217) Li, Z.-Y.; Liu, Q.-Y.; *He, S.-G. Spectroscopic Characterization of Thermal Methane Activation by Lewis-Acid-Base Pair in a Gas-Phase Pair in a Gas-Phase Metal Nitride Anion Ta₂N₃^-. ChemPhysChem 2024, e202400116.

 

2022年发表论文

(201) Cheng, X.; *Li, Z.-Y.; Mou, L.-H.; Wei, G.-P.; Liu, Q.-Y.; *He, S. G., "Size-dependent reactivity of rhodium deuteride cluster anions Rh₃D_n⁻(n = 0-3) toward dinitrogen: The prominent role of σ donation", J. Chem. Phys., 2022, 156, 064303.

(200) Yi Ren.; Yuan Yang.; Yan-Xia Zhao, *Sheng-Gui He, “Conversion of Methane with Oxygen to Produce Hydrogen Catalyzed by Triatomic Rh₃⁻ Cluster Anion”, JACS Au, 2022, 2, 197-203.

(199) Chen, L.-S.; Chen, J.-J.; *Ma, T.-M.; *Li, X.-N.; He, S.-G., "CO self-promoted oxidation by gas-phase cluster anions IrVO₄⁻", Chem.Phys.Lett., 2022, 787, 139276.

(198) Chen, J.-J.; *Li, X.-N.; Mou, L.-H.; Liu, Q.-Y.; *He, S.-G., "Catalytic Conversion of NO and CO into N₂ and CO₂ by Rhodium-Aluminum Oxides in the Gas Phase", J. Mater. Chem. A, 2022, 10, 6031.

(197) Ruan, M.; *Zhao, Y.-X.; Zhang, M.-Q.; *He, S.-G., "Methane Activation by (MoO₃)₅O^- Cluster Anions: The Importance of Orbital Orientation", Chem. Eur. J., 2022, 28, e202103321.

(196) Yang, Y.; *Zhao, Y.-X.; *He, S.-G. "Conversion of CH₄ Catalyzed by Gas Phase Ions Containing Metals", Chem. Eur. J. 2022, 28, e202200062.

(195) Li, Z.-Y.; Mou, L.-H.; Jiang, G.-D.; Liu, Q.-Y.; *He, S.-G. "¹⁵N/¹⁴N isotopic exchange in the dissociative adsorption of N₂ on tantalum nitride cluster anions Ta₃N₃^-", Chinese J. Chem. Phys., 2022, 35, 77-85.

(194) Chen, J.-J.; Liu, Y.-Z.; Liu, Q.-Y.; *Li, X.-N.; *He, S.-G., "Single Ti³⁺ Ion Catalyzes NO Reduction on Stoichiometric Titanium Oxide Cluster Anions (TiO₂)_n^– (n = 1–11)", ACS Catalysis, 2022, 12, 8768-8775.

(193) Liu, Y.-Z.; Chen, J.-J.; Mou, L.-H.; Liu, Q.-Y.; Li, Z.-Y.; *Li, X.-N.; *He, S.-G., "Reverse water–gas shift reaction catalyzed by diatomic rhodium anions", Phys. Chem. Chem. Phys. 2022, 24, 14616-14622.

(192) He, X.-Y.; Liu, Y.-Z.; Wang, S.-D.; *Lan, X.; *Li, X.-N.; He, S.-G., "Multiple CO₂ reduction mediated by heteronuclear metal carbide cluster anions RhTaC₂^–", Dalton Trans. 2022, 51,11491.

(191) Mou, L.-H.; *Li, Z.-Y.; *He, S.-G., "Recent Progress in Dinitrogen Activation by Gas-Phase Metal Species", J. Phys. Chem. Lett. 2022, 13, 4159-4169.

(190) Mou, L.-H.; Li, Y.; Wei, G.-P.; *Li, Z.-Y.; Liu, Q.-Y.; *Chen, H.; *He, S.-G., "Mutual Functionalization of Dinitrogen and Methane Mediated by Heteronuclear Metal Cluster Anions CoTaC₂^–" Chem. Sci. 2022,13, 9366.

(189)Ruan, M.; Liu, Q-Y; *Zhao, Y.-X.; Wei, G.-P.; Zhao, X.-G.; Li, Q.; *He, S.-G.,"Pyrolysis of Mass-Selected (V₂O₅)_NO⁻ (N = 1−6) Clusters in a High-Temperature Linear Ion Trap Reactor" J. Chem. Phys. 2022, 157, 114301.

(188)Chen, L.-S.; Liu, Y.-Z.; Chen, J.-J.; Wang,S.-D.; Ma, T.-M.; *Li, X.-N.; He, S.-G., "Water−Gas Shift Catalyzed by Iridium−Vanadium Oxide Clusters IrVO₂⁻ with Iridium in a Rare Oxidation State of −II", J. Phys. Chem. A 2022, 126, 5294−5301.

 

 

2021年发表论文

(187)  Lv, S.-Y.; *Liu, Q.-Y.; Zhao, Y.-X.; *He, S.-G. "Photooxidation of Isoprene by Titanium Oxide Cluster Anions with Dimensions up to a Nanosize" J. Am. Chem. Soc. 2021, 143, 3951−3958.

(186) Liu, Y.-Z.; Chen, J.-J.; *Li, X.-N.; *He, S.-G., "Activation of Carbon Dioxide by CoCD_n^– (n = 0−4) Anions" J. Phys. Chem. A 2021, 125, 3710-3717.

(185)  Liu, Y.-Z.; *Li, X.-N.; He, S.-G. "Activation of Carbon Dioxide by Gas-phase Metal Species" Chinese J. Struc. Chem. 2021, Accepted.

(184) Yang, Y.; Li, Y.-K.; *Zhao, Y.-X.; Wei, G.-P.; Ren, Y.; *Asmis, K. R.; *He, S.-G. "Catalytic Co-Conversion of CH₄ and CO₂ Mediated by Rhodium-Titanium Oxide Anions RhTiO₂⁻" Angew. Chem. Int. Ed. 2021, 60, 13788−13792

(183) Zhao, Y.-X.;# Zhao, X.-G.;# Yang, Y.; Ruan, M.; *He, S.-G., "Rhodium Chemistry: A Gas Phase Cluster Study", J. Chem. Phys. 2021, 154, 180901.

(182) Ruan, M.; *Zhao, Y.-X.; *He, S.-G., "Study on the Reaction of Nanosized Yttrium Oxide Cluster Anions with n-Butane in the Gas Phase", Acta Chim. Sinica, 2021, 79, 490-499.

(181) Wang, M.;# Chu, L.-Y.;# Li, Z.-Y.;# Messinis, A. M.; Ding, Y.-Q.; *Hu, L.; *Ma, J.-B., "Dinitrogen and Carbon Dioxide Activation to Form C–N Bonds at Room Temperature: A New Mechanism Revealed by Experimental and Theoretical Studies" J. Phys. Chem. Lett. 2021, 12, 3490-3496.

(180) Jiang, G.-D.; *Li, Z.-Y.; Mou, L.-H.; *He, S.-G., "Dual Iron Sites in Activation of N₂ by Iron-sulfur Cluster Anions Fe₅S₂⁻ and Fe₅S₃⁻", J. Phys. Chem. Lett., 2021, 12, 9269-9274.

(179) Chen, J.-J.; *Li, X.-N.; Liu, Q.-Y.; Wei, G.-P.; Yang, Y.; Li, Z.-Y.; *He, S.-G., "Water Gas Shift Reaction Catalyzed by Rhodium−Manganese Oxide Cluster Anions", J. Phys. Chem. Lett., 2021, 12, 8513-8520.

(178) Chen, L.-S.; Liu, Y.-Z.; *Li, X.-N.; Chen, J.-J.; Jiang, G.-D.; *Ma, T.-M.; *He, S.-G., "An IrVO₄⁺ Cluster Catalytically Oxidizes Four CO Molecules: Importance of Ir−V Multiple Bonding", J. Phys. Chem. Lett., 2021, 12, 6519−6525.

(177) Wei, G.-P.; *Liu, Q.-Y.; Ren, Y.; *He, S.-G., "A Ship-lock-type Reactor for Ion-molecule Reactions of Mass-selected Ions under High-pressure Conditions", Rev. Sci. Instrum., 2021, 92, 104104.

(176) Mou, L.-H.; Li, Y.; *Li, Z.-Y.; Liu, Q.-Y.; *Chen, H.; *He, S.-G., "Dinitrogen Activation by Heteronuclear Metal Carbide Cluster Anions FeTaC₂^-: A 5d Early- and 3d Late-Transition Metal Strategy", J. Am. Chem Soc., 2021, 143, 19224−19231.

(175) Han, L.-P.; Jiang, G.-D.; Li, X.-N.; *He, S.-G., “Global optimization of Ta-n clusters by deep neural network”, Chem.Phys.Lett., 2021, 785, 139118.

 

2020年发表论文

(174)  Wang, L.-N.; Li, X.-N.; *He, S.-G. "Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters" Sci. China. Mater. 2020, 63, 892–902.

(173)  Ren, Y.; *Liu, Q.-Y.; Zhao, Y.-X.; Yang, Q.; *He, S.-G. "C―C Coupling of Methane Mediated by Atomic Gold Cations under Multiple-Collision Conditions", Acta Phys. -Chim. Sin. 2020, 36, 1904026.

(172) Zhao, Y.-X.; Yang, B.; Li, H.-F.; Zhang, Y.; Yang, Y.; Liu, Q.-Y.; Xu, H.-G.; *Zheng, W.-J.; *He, S.-G., "Photoassisted Selective Steam and Dry Reforming of Methane to Syngas Catalyzed by Rhodium-Vanadium Bimetallic Oxide Cluster Anions at Room Temperature", Angew. Chem. Int. Ed. 2020, 59, 21216-21223.

(171) Li, Z.-Y.;# Li, Y.;# Mou, L.-H.; Chen, J.-J.; Liu, Q.-Y.; *He, S.-G.; *Chen, H., "A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V₃C₄^–", J. Am. Chem. Soc. 2020,142, 10747-10754.

(170) Jiang, L.-X.; *Li, X.-N.; He, S.-G., "Metal-Dependent Selectivity on the Reactions of Carbon Dioxide with Diatomic Hydride Anions MH^– (M = Co, Ni, and Cu)", J. Phys. Chem. C 2020, 124, 5928-5933.

(169) Ou, S.-H.; Chen, J.-J.; *Li, X.-N.; *Ma, T.-M.; He, S.-G., "CO Oxidation Catalyzed by the Neutral Cluster IrAl₂O₈ with Iridium in a High Oxidation State of VI", J. Phys. Chem. C 2020,124, 8869-8875.

(168) Wang, M.-M.; Zhao, Y.-X.; *Ding, X.-L.; Li, W.; *He, S.-G., "Methane activation by heteronuclear diatomic AuRh⁺ cation: comparison with homonuclear Au₂⁺ and Rh₂⁺", Phys. Chem. Chem. Phys. 2020, 22, 6231-6238.

(167) Jiang, G.-D.; Mou, L.-H.; Chen, J.-J.; *Li, Z.-Y.; *He, S.-G., "Reactivity of Neutral Tantalum Sulfide Clusters Ta₃S_n (n=0-4) with N₂", J. Phys. Chem. A 2020,124, 7749-7755.

(166) *Li, X.-N.; Jiang, L.-X.; Liu, Q.-Y.; Ren, Y.; Wei, G.-P., "Hydrogen-Assisted C-C Coupling on Reaction of CuC₃H^– Cluster Anion with CO", Chin. J. Chem. Phys. 2020,33, 628-634.

(165) Mou, L.-H.; Jiang, G.-D.; *Li, Z.-Y.; *He, S.-G., "Activation of dinitrogen by gas-phase species", Chin. J. Chem. Phys. 2020, 33, 507-520.

(164) Mou, L.-H.;# Li, Y.;# *Li, Z.-Y.; Liu, Q.-Y.; Ren, Y.; *Chen, H.; *He, S.-G., "Dinitrogen Activation and Functionalization by Heteronuclear Metal Cluster Anions FeV₂C₂^– at Room Temperature", J. Phys. Chem. Lett. 2020,11, 9990-9994.

(163) Liu, Y.-Z.; *Li, X.-N.; *He, S.-G., "Reactivity of Iron Hydride Anions Fe₂H_n^– (n = 0–3) with Carbon Dioxide", J. Phys. Chem. A 2020, 124, 8414-8420.

 

2019年发表论文

(162) Chen, J.-J.; *Li, X.-N.; Chen, Q.; Liu, Q.-Y.; Jiang, L.-X.; He, S.-G., "Neutral Au₁-Doped Cluster Catalysts AuTi₂O_3-6 for CO Oxidation by O₂", J. Am. Chem. Soc. 2019, 141, 2027-2034.

(161) Zhang, M.-Q.; Lv, S.-Y.; *Li, X.-N.; *He, S.-G., "Cooperative Desorption of H₂O and CO from Photo-Excited Cobalt Oxide Clusters: The Evidence of Photo-Catalytic Coupling", Chem. Phys. Lett. 2019, 219, 72-77. 

(160) Ou, S.-H.; Chen, J.-J.; *Li, X.-N.; Wang, L.-N.; *Ma, T.-M.; *He, S.-G., "CO Oxidation by Neutral Gold-Vanadium Oxide Clusters", Chin. J. Chem. Phys. 2019, 32, 207-212.

(159) Lv, S.-Y.; *Liu, Q.-Y.; Zhao, Y.-X.; Zhang, M.-Q.; Jiang, L.-X.; *He, S.-G., "Formaldehyde Generation in Photooxidation of Isoprene on Iron Oxide Nanoclusters", J. Phys. Chem. C 2019, 123, 5120-5127. 

(158) Chen, Q.; Jiang, L.-X.; Li, H.-F.; Chen, J.-J.; *Zhao, Y.-X.; *He, S.-G., "Thermal Activation of Methane by Diatomic Vanadium Boride Cations", Acta Phys.-Chim. Sin. 2019, 35, 1014-1020. 

(157) Wang, L.-N.; *Li, X.-N.; He, S.-G., "Catalytic CO Oxidation by Noble-Metal-Free Ni₂VO_4,5⁻ Clusters, A CO Self-Promoted Mechanism", J. Phys. Chem. Lett. 2019, 10, 1133-1138. 

(156) Li, Z.-Y.; Mou, L.-H.; Wei, G.-P.; Ren, Y.; Zhang, M.-Q.; Liu, Q.-Y.; *He, S.-G., "C-N Coupling in N₂ Fixation by the Ditantalum Carbide Cluster Anions Ta₂C₄⁻", Inorg. Chem. 2019, 58, 4701-4705. 

(155) *Zhao, Y.-X.; Wang, M.-M.; Zhang, Y.; *Ding, X.-L.; He, S.-G., "Activity of Atomically Precise Titania Nanoparticles in CO Oxidation", Angew. Chem. Int. Ed. 2019, 58, 8002-8006. 

(154) Wang, L.-N.; Chen, J.-J.; *Li, X.-N.; Liu, Y.-Z.; He, S.-G., "Doping Effects on the Reactivity of the MVO₅⁻ (M = V-Zn) Clusters in CO Oxidaton Reaction", J. Phys. Chem. C 2019, 123, 14180-14186. 

(153) Ren, Y.; Yang, Y; *Zhao, Y.-X.; *He, S.-G., "Size-Dependent Reactivity of Rhodium Cluster Anions toward Methane", J. Phys. Chem. C 2019, 123, 17035−17042. 

(152) Mou, L.-H.; *Li, Z.-Y.; Liu, Q.-Y.; *He, S.-G., "Size-Dependent Association of Cobalt Deuteride Cluster Anions Co₃D_n⁻ (n = 0-4) with Dinitrogen", J. Am. Soc. Mass Spectrom. 2019, 30(10), 1956-1963. 

(151) Lu, X.-W.; Jiang, L.-X.; Liu, J.; Yang, Y.; *Liu, Q.-Y.; Ren, Y.; Li, X.; *He, S.-G., "Sensitive Detection of Gas-Phase Glyoxal by Electron Attachment Reaction Ionization Mass Spectrometry", Anal. Chem. 2019, 91, 12688-12695.

(150) Lv, S.-Y.; *Liu, Q.-Y.; Chen, J.-J.; *He, S.-G., "Oxidation of Isoprene by Neutral Iron Oxide Nanoclusters in the Gas Phase" J. Phys. Chem. C 2019, 123, 25949-25956. 

(149) Wang, Z.-C.; Li, Y.-K.; He, S.-G.; Bierbaum M. V., "The HNO⁻radical anion: A proposed intermediate in diazeniumdiolate synthesis using nitric oxide and alkoxides", Eur. J. Mass. Spectrom. 2019, 25, 82-85. 

(148) Yang, Y.; Yang, B.; *Zhao, Y.-X.; Jiang, L.-X.; Li, Z.-Y.; Ren, Y.; Xu, H.-G., *Zheng, W.-J., *He, S.-G., "Direct Conversion of Methane with Carbond Dioxide Mediated by RhVO₃⁻ Cluster Anions", Angew. Chem. Int. Ed. 2019, 58, 17287-17292. 

(147) Cheng, X.; *Li, Z.-Y.; Mou, L.-H.; Ren, Y.; Liu, Q.-Y.; *Ding, X.-L.; *He, S.-G., "Side-on-End-on Coordination of Dinitrogen on a Poly-Nuclear Vanadium Cluster Anion V₅N₅⁻", Chem. Eur. J 2019, 25, 16523-6527. 

(146) Zhao, Y.; Cui, J.-T.; Wang, M.; Valdivielso D. Y.; *Fielicke A.; *Hu, L.-R.; Cheng X.; Liu, Q.-Y.; Li, Z.-Y.; He, S.-G.; *Ma, J.-B., "Dinitrogen Fixation and Reduction by Ta₃N₃H_0,1^– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity", J. Am. Chem. Soc. 2019, 141, 12592-12600.  

(145) Li, X.-N.; Wang, L.-N.; Mou, L.-H.; *He, S.-G., "Catalytic CO Oxidation by Gas-Phase Metal Oxide Clusters" J. Phys. Chem. A 2019, 123, 9257-9267.  

(144) Chen, Q.; *Zhao, Y.-X.; Chen, J.-J.; Jiang, L.-X.; *He, S.-G., "Selective Generation of Free Hydrogen Atoms in the Reaction of Methane with Diatomic Gold Boride Cations" Z. Phys. Chem. 2019, 233, 785-797.  

(143) Li, X.-N.; Jiang, L.-X.; Wang, L.−N.; Ou, S.-H.; Zhang, M.-Q.; Yang, Y.; Ma, T.-M.; *He, S.-G., "An Eight-Atom Iridium−Aluminum Oxide Cluster IrAlO₆⁺ Catalytically Oxidizes Six CO Molecules" J. Phys. Chem. Lett. 2019, 10, 7850-7855.  

 

2018年发表论文

(142) Jiang, L.-X.; Liu, Q.-Y.; *Li, X.-N.; *He, S.-G., "Design and Application of A High-Temperature Linear Ion Trap Reactor", J. Am. Soc.Mass Spectrom. 2018, 29, 78-84. 

(141) Zou, X.-P.; Li, Z.-Y.; *Li, X.-N.; Wang, L.-N.; Li, H.-F.; *Ma, T.-M.; *He, S.-G., "Consecutive Oxidation of Three H₂ Molecules by A Gold-Vanadium Oxide Cluster Cation AuVO₄⁺", Top. Catal. 2018, 61, 28-34. 

(140) Wang, L.-N.; *Li, X.-N.; Jiang, L.-X.; Yang, B.; Liu, Q.-Y.; Xu, H.-G.; *Zheng, W.-J.; *He, S.-G., "Catalytic CO Oxidation by O₂ Mediated by Noble-Metal-Free Cluster Anions Cu₂VO_3-5⁻", Angew. Chem. Int. Ed. 2018, 57, 3349-3353. 

(139) Li, H.-F.; Jiang, L.-X.; *Zhao, Y.-X.; Liu, Q.-Y.; Zhang, T.; *He, S.-G., "Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC₃⁻ under High-Temperature Conditions", Angew. Chem. Int. Ed. 2018, 57, 2662-2666. 

(138) Zou, X.-P.; Wang, L.-N.; *Li, X.-N.; Liu, Q.-Y.; Zhao, Y.-X.; *Ma, T.-M.; *He, S.-G., "Noble-Metal Free Single Atom Catalysts CuAl₄O_7-9⁻ for CO Oxidation by O₂", Angew. Chem. Int. Ed. 2018, 57,10989-10993. 

(137) Mou, L.-H.; Liu, Q.-Y.; Zhang, T.; *Li, Z.-Y.; *He, S.-G., "Reactivity of Tantlum Carbide Cluster Anions TaC_n⁻ (n = 1-4) with Dinitrogen", J. Phys. Chem. A 2018, 122, 3489-3495. 

(136) Chen, J.-J.; Yang, Y.; *Zhao, Y.-X.; *He, S.-G., "VUV Ionization Induced Reaction of Neutral Au₂Al₂O₃ Clusters with Methane", J. Phys. Chem. C 2018, 122, 6159-6165. 

(135) Li, Y.-K.; *Zhao, Y.-X.; *He, S.-G., "Selective Conversion of Methane by Rh₁-Doped Aluminum Oxide Cluster Anions RhAl₂O₄⁻: A Comparision with the Reactivity of PtAl₂O₄⁻", J. Phys. Chem. A 2018, 122, 3950-3955. 

(134) Chen, Q.; *Zhao, Y.-X.; Jiang, L.-X.; Li, H.-F.; Chen, J.-J.; Zhang, T.; Liu, Q.-Y.; *He, S.-G., "Thermal Activation of Methane by Vanadium Boride Cluster Cations VB_n⁺ (n = 3-6)", Phys. Chem. Chem. Phys. 2018, 20, 4641-4645. 

(133) Zhao, Y.-X.; *He, S.-G., "A Breakthrough in Direct Conversion of Methane to Oxygenates under Mild Conditions", Science China Materials 2018, 61, 1012-1014. 

(132) Lu, X.-W.; Ren, Y.; *Liu, Q.-Y.; Zhang, T.; Jiang, L.-X.; Wei, G.-P.; *He, S.-G., "Electron Attachment Reaction Ionization of Gas-Phase Methylglyoxal", Anal. Chem. 2018, 90, 13467-13474. 

(131) Chen, Q.; *Zhao, Y.-X.; Jiang, L.-X.; Chen, J.-J.; *He, S.-G., "Coupling of Methane and Carbon Dioxide Mediated by Diatomic Copper Boride Cations", Angew. Chem. Int. Ed. 2018, 57, 14134-14138.

(130) Liu, Y.-Z.; Jiang, L.-X.; *Li, X.-N.; Wang, L.-N.; Chen, J.-J.; *He, S.-G., "Gas-Phase Reactions of Carbon Dioxide with Copper Hydride Anions Cu₂H₂⁻: Temperature-Dependent Transformation", J. Phys. Chem. C 2018, 122, 19379-19384. 

(129) Chen, Y.-M.; Wang, L.-N.; Chen, J.-J.; Chen, Q.; Jiang, L.-X.; *Zhao, Y.-X.; *Ding, X.-L.; *He, S.-G., "Mechanistic Variants in Methane Activation Mediated by Gold(I) Supported on Silicon Oxide Clusters", Chem. Eur. J. 2018, 24, 17506-17512. 

(128) Zhao, Y.-X.; Li, Z.-Y.; Yang, Y.; *He, S.-G., "Methane Activation by Gas Phase Atomic Clusters", Acc. Chem. Res. 2018, 51, 2603-2610. 

(127) Jiang, L.-X.; *Li, X.-N.; Li, Z.-Y.; Li, H.-F.; *He, S.-G., "H₂ Dissociation by Au₁-Doped Closed-Shell Titanium Oxide Cluster Anions", Chin. J. Chem. Phys. 2018, 31, 457-462. 

 

2017年发表论文

(126) Jiang, L.-X.; Zhao, C.; *Li, X.-N.; *Chen, H.; *He, S.-G., "Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions", Angew. Chem. Int. Ed, 2017, 56, 4187-4191 (Cover, VIP). 

(125) Zhang, M.-Q.; *Zhao, Y.-X.; Liu, Q.-Y.; Li, X.-N.; *He, S.-G., "Does Each Atom Count in the Reactivity of Vanadia Nanoclusters?", J. Am. Chem. Soc. 2017, 139, 342-347. 

(124) Li, H.-F.; *Zhao, Y.-X.; Yuan, Z.; Liu, Q.-Y.; Li, Z.-Y.; Li, X.-N.; Ning, C.-G.; *He, S.-G., "Mathane Activtion by Tantalum Carbide Cluster Anions Ta₂C₄⁻", J. Phys. Chem. Lett. 2017, 8, 605-610. 

(123) Li, X.-N.; Zou, X.-P.; *He, S.-G., "Metal-Mediated Catalysis in the Gas Phase, A Review", Chinese J. Catal. 2017, 38, 1515.

(122) Zhou, X.-H.; *Li, Z.-Y.; Jiang, L.-X.; *He, S.-G.; *Ma, T.-M., "Methane Activation Mediated by Dual Gold Atoms Doped in Aluminium Oxide Cluster Cations Au₂Al₂O₃⁺", Chemistry Select. 2017, 2, 991-996. 

(121) Chen, J.-J.; Zhang, T.; Zhang, M.-Q.; Liu, Q.-Y.; *Li, X.-N.; *He, S.-G., "Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene", Chem. Eur. J. 2017, 23, 15820-15826. 

(120) Chen, J.-J.; Yuan, Z.; Li, X.-N.; *He, S.-G., "A VUV Photoionization Time-of-Flight Mass Spectrometer for the Formation, Distribution, and Reaction of Nano-Sized Neutral Metal Oxide Clusters", Int. J. Mass Spectrom. 2017, 422, 98-104. 

(119) Zhang, Y.; *Li, Z.-Y.; Zhao, Y.-X.; Li, H.-F.; *Ding, X.-L.; Zhang, H.-Y.; *He, S.-G., "H₂ Oxidation Mediated by Au₁-Doped Vanadium Oxide Cluster Cation AuV₂O₅⁺: A Compartive Study with AuCe₂O₄⁺", J. Phys. Chem. A 2017, 121, 4069-4075. 

(118) Zhang, T.; Li, Z.-Y.; Liu, Q.-Y.; *He, S.-G., "Chemical Ionization of Large Linear Alkanes and Small Oxidized Volatile Organic Compounds by the Reactions with Atomic Gold Cations", Anal. Chem. 2017, 89, 9083-9090. 

(117) Zhang, L.; *Zhang, X.-B.; Zhang, D.-D.; *He, S.-G., "Theoretical Prediction of the Synthesis of 2,3-Dihydropyridines through Ir(III) Catalysed Reaction of Unsaturated Oximes with Alkenes", RSC Adv. 2017, 7, 5679-5659. 

(116) Hu, J.-C.; Xu, L.-L.; Li, H.-F.; Valdivielso, D.-Y.; Fielicke, A.; He, S.-G.; *Ma, J.-B., "Liberation of Three Dihydrogens from Two Ethene Molecules as Mediated by the Tantalum Nitride Anion Cluster Ta₃N₂⁻ at Room Temperature", Phys. Chem. Chem. Phys. 2017, 19, 3136-3142. 

(115) Yan, Y.; Shi, W.-D.; Yuan, Z.; He, S.-G.; Li, D.-M.; Meng, Q.-B.; Ji, H.-W.; Chen, C.-C.; *Ma, W.-H.; *Zhao, J.-C., "The Formation of Ti-H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices", J. Am. Chem. Soc. 2017, 139, 2083-2089. 

(114) *Yan, X.-J., Ma, K.-L.; Zou, W.-X.; He, S.-G.; An, J.-B.; Yang, F.-M.; *Dong, L., "Influence of Preparation Methods on the Physicochemical Properties and Catalytic Performation of MnOx-CeO₂ Catalysts for NH₃-SCR at Low Temperature", Chinese J. Catal. 2017, 38, 146-159. 

(113) Li, Y.-K.; Wang, Z.-C.; He, S.-G.; *Bierbaum, V.-M., "Reactions of Sulfur- and Oxygen-Containing Anions with Hydrogen Atoms: A Comparative Study", J. Phys. Chem. Lett. 2017, 8, 5725-5729. 

 

2016年发表论文

(112) Li, X.-N.; Zhang, H.-M.; Yuan, Z.; *He, S.-G., "A Nine-Atom Rhodium-Aluminum Oxide Cluster Oxidizes Five Carbon Monoxide Molecules", Nat. Commun, 2016, 7, 11404. 

(111) Zhao, Y.-X.; Li, X.-N.; Yuan, Z.; Liu, Q.-Y.; *Shi, Q.; *He, S.-G., "Methane Activation by Gold-Doped Titanium Oxide Cluster Anions with Closed-Shell Electronic Structures", Chem. Sci. 2016, 7, 4730-4735. 

(110) Li, X.-N.; Li, Z.-Y.; Li, H.-F.; *He, S.-G., "Muliple CO Oxidation Promoted by Au₂-dimer in Au₂TiO₄⁻ Cluster Anions", Chem. Eur. J. 2016, 22, 9024-9029. 

(109) *Ma, J.-B.; Xu, L.-L.; Liu, Q.-Y.; *He, S.-G., "Activation of Methane and Ethane as Mediated by the Tiatomic Anion HNbN⁻: Electronic Structure Similarity with a Pt Atom ", Angew. Chem. Int. Ed. 2016, 55, 4947. 

(108) Liu, Q.-Y.; *Ma, J.-B.; Li, Z.-Y.; Zhao, C.; Ning, C.-G.; *Chen, H.; *He, S.-G., "Activation of Methane Promoted by Adsorption of CO on Mo₂C₂⁻ Cluster Anions", Angew. Chem. Int. Ed. 2016, 55, 5760. 

(107) Li, Z.-Y.; Li, H.-F.; *Zhao, Y.-X.; *He, S.-G., "Gold (III) Mediated Activation and Transformation of Methane on Au₁-doped Vanadium Oxide Cluster Cations AuV₂O₆⁺", J. Am. Chem. Soc. 2016, 138, 9437-9443.

(106) Liu, Q.-Y.; Yuan, Z.; Zhao, Y.-X.; *He, S.-G., "Photo-Induced Reaction of Ethene Bound to Vanadia Nanoparticles [(V₂O₅)_nC₂H₄(n =2-20)]⁻ in the Gas Phase", J. Phys. Chem. C 2016, 120, 17081-17086. 

(105) Zhou, X.-H.; *Li, Z.-Y.; *Ma, T.-M.; He, S.-G., "Consecutive H₂ Oxidation Mediated by Au₂VO₄⁺ Clusters", J. Phys. Chem. C 2016, 120, 10452-10459. 

(104) Jiang, L.-X.; *Li. X.-N.; Li, H.-F.; Zhou, Z.-X.; *He, S.-G., "Generation of Hydroxyl Radicals in the Reaction of Dihydrogen with AuNbO₄⁺ Cluster Cations", Chem. Asian J. 2016, 11, 2730-2734. 

(103) Zhang, T.; Li, Z.-Y.; Zhang, M.-Q.; *He, S.-G., "Gas-Phase Reactions of Atomic Gold Cations with Linear Alkanes (C2-C9)", J. Phys. Chem. A 2016, 120, 4285-4293.

(102) Zhao, Y.-X.; Liu, Q.-Y.; Zhang, M.-Q.; *He, S.-G., "Reactions of Metal Cluster Anions with Inorganic and Organic Molecules in the Gas Phase", Dalton Trans. 2016, 45, 11471-11495. 

(101) Ma, J.-B.; Meng, J.-H.; *He, S.-G., "Methane Activation Mediated by a Series of Cerium-Vanadium Bimetallic Oxide Cluster Cations: Tuning Reactivity by Doping", ChemPhysChem 2016, 17, 1112-1118.

(100) 赵艳霞, *何圣贵, "异核氧化物团簇与小分子的反应研究", Progress in Chemistry 2016, 28, 401-414. 

(99) *Ma, J.-B.; Xu, L.-L.; Meng, J.-H.; *He, S.-G., "Dehydrogenation of Propylene Mediated by CeVO₄⁺: An Interesting Example for the Chemistry of Binary Ce-V Transition-Metal Oxide Cluster Cations", Int. J. Mass Spectrom. 2016, 401, 39-45. 

(98) Li, Y.-K.; Li, Z.-Y.; *Zhao, Y.-X.; Liu, Q.-Y.; Meng, J.-H.; *He, S.-G., "Activation and Transformation of Ethane by Au₂VO₃⁺ Clusters with Closed-Shell Electronic Structures", Chem. Eur. J. 2016, 22, 1825-1830. 

(97) Zhou, Z.-X.; Wang, L.-N.; *Li, Z.-Y.; He, S.-G.; *Ma, T.-M., "Oxidation of SO₂ to SO₃ by Cerium Oxide Cluster Cations Ce₂O₄⁺ and Ce₃O₆⁺". J. Phys. Chem. A 2016, 120, 3843-3848. 

(96) Yuan, Z.; Liu, Q.-Y.; *Li, X.-N.; *He, S.-G., "Formation, Distribution, and Photoreaction of Nano-sized Vanadium Oxide Cluster Anions", Int. J. Mass Spectrom. 2016, 407, 62-68. 

(95) Li, Y.-K.; Yuan, Z.; *Zhao, Y.-X.; Zhao, C.; Liu, Q.-Y.; *Chen, H.; *He, S.-G., "Thermal Methane Conversion to Syngas Mediated by Rh₁‑Doped Aluminum Oxide Cluster Cations RhAl₃O₄⁺", J. Am. Chem. Soc. 2016, 138, 12854-12860. 

(94) Hu, J.-C.; Xu, L.-L.; Hou, X.-Y.; Li, H.-F.; *Ma, J.-B.; He, S.-G., "Origin of the Different Reactivity of the Triatomic Anions HMoN⁻ and ZrNH⁻ toward Alkane: Compositions of the Active Orbitals", J. Phys. Chem. A 2016, 120, 7786-7791. 

(93) 张梅琦, 赵艳霞, *何圣贵, "贵金属及其掺杂团簇与甲烷反应研究进展", 化学通报，2016, 7, 395-402. 

 

2015年发表论文

(92) Wang, L.-N.; Zhou, Z.-X.; Li, X.-N.; Ma, T.-M.; He, S.-G., "Thermal Conversion of Methane to Formaldehyde Promoted by Gold in AuNbO₃⁺ Cluster Cations", Chem. Eur. J. 2015, 21, 6957-6961. 

(91) Liu, Q.-Y.; Hu, L.-R.; Li, Z.-Y.; Ning, C.-G.; Ma, J.-B.; Chen, H.; He, S.-G.; "Photoelectron imaging spectroscopy of MoC⁻ and NbN⁻ diatomic anions:A comparative study", J. Chem. Phys. 2015, 142, 164301.

(90) Li, H.-F.; Li, Z.-Y.; Liu, Q.-Y.; Li, X.-N.; Zhao, Y.-X.; He, S.-G., "Methane Activation by Iron-Carbide Cluster Anions FeC₆⁻", J. Phys. Chem. Lett. 2015, 6, 2287-2291. 

(89) Li, Y.-K.; Meng, J.-H.; He, S.-G., "Generation of free hydrogen atoms in thermal reaction of ethane with AuNbO₃⁺ cluster cations", Int. J. Mass, Spectrom. 2015, 381-382, 10-16. 

(88) Liu, Q.-Y.; Hu, L.-R.; Chen, H.; He, S.-G., "Photoelectron imaging spectroscopy of ZrO⁻ diatomic anion", Chin. J. Chem. Phys. 2015, 28, 452-458.

(87) Li, Z.-Y.; Hu, L.-R.; Liu, Q.-Y.; Ning, C.-G.; Chen, H.; He, S.-G.; Yao, J.-N., "C-H Bong Activation by Early Transition Metal Carbide Cluster Anion MoC₃⁻", Chem. Eur. J. 2015, 21, 17748-17756. 

(86) Meng, Z.; Han, Y.; Wang, L.-N.; Xing, J.-F.; He, S.-G.; Chen, C.-F., "Stepwise Motion in a Multivalent [2](3)Catenane", J. Am. Chem. Soc. 2015, 137, 9739-9745. 

(85) 何圣贵, "欧美科学家使用飞秒X 射线激光检测一氧化碳氧化过程的过渡态", 科学通报, 2015, 60, 2149-2150.

(84) Wang, L.-N.; Li, Z.-Y.; Liu, Q.-Y.; Meng, J.-H.; He, S.-G.; Ma, T.-M., "CO oxidation promoted by gold dimer in Au₂VO₃⁻ and Au₂VO₄⁻ clusters", Angew. Chem. Int. Ed. 2015, 54, 11720-11724. 

(83) Li, X.-N.; Yuan, Z.; Meng, J.-H.; Li, Z.-Y.; He, S.-G., "Catalytic CO Oxidation on Single Pt-Atom Doped Aluminum Oxide Clusters:  Electronegativity-Ladder Effect ", J. Phys. Chem. C 2015, 119, 15414-15420. 

 

2014年发表文章

(82) Meng, J.-H.; *He, S.-G., "Thermal Dihydrogen Activation by a Closed-Shell AuCeO₂⁺ Cluster" J. Phys. Chem. Lett. 2014, 5, 3890-3894. 

(81) Li, Z.-Y.; Yuan, Z.; *Li, X.-N.; Zhao, Y.-X.; *He, S.-G., "CO Oxidation Catalyzed by Single-Au Atoms Supported on Aluminum Oxide Clusters" J. Am. Chem. Soc. 2014, 136, 14307-14313. 

(80) Li, X.-N.; Yuan, Z.; *He, S.-G., "CO Oxidation Promoted by Gold Atoms Supported on Titanium Oxide Cluster Anions" J. Am. Chem. Soc. 2014, 136, 3617-3623.

(79) Zhao, Y.-X.; Li, Z.-Y.; Yuan, Z.; Li, X.-N.; *He, S.-G., " Thermal Methane Conversion to Formaldehyde Promoted by single Platinum Atoms in PtAl₂O₄⁻ cluster Anions" Angew. Chem. Int. Ed. 2014, 53, 9482-9486.

(78) Yuan, Z.; *Li, X.-N.; *He, S.-G., "CO Oxidation Promoted by Gold Atoms Loosely Attached in AuFeO₃⁻ Cluster Anions" J. Phys. Chem. Lett. 2014, 5, 1585-1590. 

(77) Tian, L.-H.; Meng, J.-H.; Wu, X.-N.; *Zhao, Y.-X.; Ding, X.-L.; *He, S.-G.; *Ma, T.-M., "Reactivity of Oxygen Radical Anions Bound to Scandia Nanoparticles in the Gas Phase: C-H Bond Activation" Chem. Eur. J. 2014, 20, 1167-1175. 

(76) Meng, J.-H.; Deng, X.-J.; Li, Z.-Y.; *He, S.-G.; *Zheng, W.-J., "Thermal Methane Activation by La₆O₁₀⁻ cluster anions" Chem. Eur. J. 2014, 20, 5580-5583. 

(75) Li, Z.-Y.; Yuan, Z.; *Zhao, Y.-X.; *He, S.-G., "Methane Activation by Diatomic Molybdenum Carbide Cations" Chem. Eur. J. 2014, 20, 4163-4169. 

(74) Jia, M.-Y.; *Luo, Z.-X.; *He, S.-G.; Ge, M.-F., "Oxygen-Sulfur Exchange and the Gas-Phase Reactivity of Cobalt Sulfide Cluster Anions with Molecular Oxygen" J. Phys. Chem. A 2014, 118, 8163-8169.

(73) Jia, M.-Y.; Bo, X.; Deng, K.; *He, S.-G.; *Ge, M.-F., "Consecutive Oxygen-for-Sulfur Exchange Reactions between Vanadium Oxide Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. A 2014, 118, 8106-8114. 

(72) Yuan, Z.; Li, Z.-Y.; Zhou, Z.-X.; Liu, Q.-Y.; Zhao, Y.-X.; *He, S.-G., "Thermal Reactions of (V₂O₅)_nO^– (n = 1–3) Cluster Anions with Ethylene and Propylene: Oxygen Atom Transfer Versus Molecular Association" J. Phys. Chem. C 2014, 118, 14967-14976.

(71) Liu, Q.-Y.; *He, S.-G., "Oxidation of Carbon Monoxide on Atomic Clusters." Chem. J. Chinese U. 2014, 35, 665-688. 

(70) Xu, B.; Meng, J.-H.; *He, S.-G., "Photoreaction Study of Methanol Adsorption Complexes on VO₂(V₂O₅)_n⁺ (n = 1–3) Clusters at 355 nm" J. Phys. Chem. C 2014, 118, 18488-18495.

 

2013年发表文章

(69) Xu, B.; Zhao, Y.-X.; Ding, X.-L.; Liu, Q.-Y.; *He, S.-G., "Collision-Induced Dissociation and Infrared Photodissociation Studies of Methane Adsorption on V₅O₁₂⁺ and V₅O₁₃⁺ Clusters" J. Phys. Chem. A 2013, 117, 2961-2970. 

(68) Ma, J.-B.; Xu, B.; Meng, J.-H.; Wu, X.-N.; Ding, X.-L.; Li, X.-N.; *He, S.-G., "Reactivity of Atomic Oxygen Radical Anions Bound to Titania and Zirconia Nano-Particles in the Gas Phase: Low-Temperature Oxidation of Carbon Monoxide" J. Am. Chem. Soc. 2013, 135, 2991-2998. (cover article) 

(67) Wu, X.-N.; Li, X.-N.; Ding, X.-L.; *He, S.-G., "Activation of Multiple C-H Bonds Promoted by Gold in AuNbO₃⁺ Clusters" Angew. Chem. Int. Ed. 2013, 52, 2444-2448. 

(66) Ma, J.-B.; Wang, Z.-C.; Schlangen, M.; *He, S.-G.; *Schwarz, H., "On the Origin of the Surprisingly Sluggish Redox Reaction of the N₂O/CO Couple Mediated by [Y₂O₂]^+· and [YAlO₂]^+· Cluster Ions in the Gas Phase" Angew. Chem. Int. Ed. 2013, 52, 1226-1230.

(65) Xu, B.; *Zhao, Y.-X.; Ding, X.-L.; *He, S.-G., "Reactions of Sc₂O₄⁻  and La₂O₄⁻ Clusters with CO: A comparative study"  Int. J. Mass Spectrom. 2013, 334, 1-7.

(64) Tian, L.-H.; *Ma, T.-M.; *Li, X.-N.; *He, S.-G., "C-H bond Activation by Aluminum Oxide Cluster Anions, An Experimental and Theoretical Study" Dalton Trans. 2013, 42, 11205-11211.

(63) Yuan, Z.; *Zhao, Y.-X.; Li, X.-N.; *He, S.-G., "Reactions of V₄O₁₀⁺ Cluster Ions with Simple Inorganic and Organic Molecules" Int. J. Mass Spectra. 2013, 354-355, 105-112. 

(62) Jia, M.-Y.; Ding, X.-L.; *He, S.-G.; *Ge, M.-F., " Experimental and Theoretical Study of the Reactions between MO₂⁻ (M = Fe, Co, Ni, Cu, and Zn) Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. A 2013, 117, 8377-8387. 

(61) Meng, J.-H.; *Zhao, Y.-X.; *He, S.-G., "Reactivity of Stoichiometric Lanthanum Oxide Cluster Cations in C-H Bond Activation" J. Phys. Chem. C 2013, 117, 17548-17556. 

(60) Jia, M.-Y.; *He, S.-G.; *Ge, M.-F., "Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide" Chin. J. Chem. Phys. 2013, 26, 679-686. 

(59) *Zhao, Y.-X.; Xu, B.; Ding, X.-L.; *He, S.-G., "Fabrication and Optical Properties of Pyrene-Eu Hybrid Materials" J. Nanosci. Nanotechnol. 2013, 13, 819-823. 

(58) Xu, H.-G.; *Li, X.-N.; Kong, X.-Y.; He, S.-G.; *Zheng, W.-J., "Interaction of TiO⁺ with Water: Infrared Photodissociation Spectroscopy and Density Functional Calculations" Phys. Chem. Chem. Phys. 2013, 15, 17126-17133. 

 

2012年发表文章

(57) Ma, J.-B.; Wang, Z.-C.; *Schlangen, M.; *He, S.-G.; *Schwarz, H., "Thermal Reactions of YAlO₃⁺ with Methane: Increasing the Reactivity of Y₂O₃⁺ and the Selectivity of Al₂O₃⁺ by Doping" Angew. Chem. Int. Ed. 2012, 51, 5991-5994. 

(56) Ding, X.-L.; Li, Z.-Y.; Meng, J.-H.; Zhao, Y.-X.; *He, S.-G., "Density-functional global optimization of (La₂O₃)_n clusters" J. Chem. Phys. 2012, 137, 214311. 

(55) Huang, J.-H.; Zhao, Y.; Ding, X.-L.; Jia, H.; Jing, B.; Zhang, Z.-G.; *Zhan. C.-L.; He, S.-G.; *Pei, Q.-B., Li, Y.-F.; Liu, Y.-Q.; *Yao, J.-N., "Synthesis and charge-transporting properties of electron-deficient CN₂-fluorene based D-A copolymers" Polym. Chem. 2012, 3, 2170-2177. 

(54) Jia, M.-Y.; Xu, B.; Ding, X.-L.; *He, S.-G.; *Ge, M.-F., "Experimental and Theoretical Study of the Reactions between Manganese Oxide Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. C 2012, 116, 24184-24192. 

(53) Jia, M.-Y.; Xu, B.; Ding, X.-L.; Zhao, Y.-X.; *He, S.-G.; *Ge, M.-F., "Experimental and Theoretical Study of the Reactions between Vanadium Oxide Cluster Cations and Hydrogen Sulfide" J. Phys. Chem. C 2012, 116, 9043-9048.

(52) Li, X.-N.; Xu, B.; Ding, X.-L.; *He, S.-G., "Interaction of vanadium oxide cluster anions with water: an experimental and theoretical study on reactivity and mechanism" Dalton Trans. 2012, 41, 5562-5570.

(51) Li, X.-N.; Wu, X.-N.; Ding, X.-L.; *He, S.-G., "Reactivity control of C-H bond activation over vanadium-silver bimetallic oxide cluster cations" Chem. Eur. J. 2012, 18, 10998-11006. 

(50) Tian, L.-H.; Zhao, Y.-X.; Wu, X.-N.; Ding, X.-L.; *He, S.-G.; *Ma, T.-M., "Structures and Reactivity of Oxygen-Rich Scandium Cluster Anions ScO_3-5⁻" ChemPhysChem 2012, 13, 1282-1288. 

(49) Ding, X.-L.; Wu, X.-N.; Zhao, Y.-X.; *He, S.-G., "C-H Bond Activation by Oxygen-Centered Radicals over Atomic Clusters" Acc. Chem. Res. 2012, 45, 382-390. 

(48) Ma, J.-B.; Zhao, Y.-X.; *He, S.-G.; *Ding, X.-L., "Experimental and Theoretical Study of the Reactions between Vanadium Oxide Cluster Cations and Water" J. Phys. Chem. A 2012, 116, 2049-2054.

(47) Wu, X.-N.; Xu, B.; Meng, J.-H.; *He, S.-G., "C-H Bond Activation by Nanosized Scandium Oxide Clusters in Gas-Phase" Int. J. Mass Spectrom. 2012, 310, 57-64. 

 

2011年发表文章

(46) Zhao, Y.-X.; Wu, X.-N.; Ma, J.-B.; *He, S.-G.; *Ding, X.-L., "Characterization and reactivity of oxygen-centred radicals over transition metal oxide clusters" Phys. Chem. Chem. Phys. 2011, 13, 1925-1938. 

(45) Ding, X.-L.; Wu, X.-N.; Zhao, Y.-X.; Ma, J.-B.; *He, S.-G., "Double-oxygen-atom transfer reaction in the reaction of Ce_mO_2m⁺ (m = 2-6) with C₂H₂" ChemPhysChem 2011, 12, 2110-2117. 

(44) Li, Z.-Y.; Zhao, Y.-X.; Wu, X.-N.; *Ding, X.-L.; *He, S.-G., "Methane Activation by Yttrium-Doped Vanadium Oxide Cluster Cations: Local Charge Effects" Chem. Eur. J. 2011, 17, 11728-11733.

(43) Zhao, Y.-X.; Yuan, J.-Y.; Ding, X.-L.; *He, S.-G.; *Zheng, W.-J., "Electronic Structure and Reactivity of a Biradical Cluster: Sc₃O₆⁻" Phys. Chem. Chem. Phys. 2011, 13, 10084-10090. 

(42) Wu, X.-N.; Ding, X.-L.; Bai, S.-M.; Xu, B.; *He, S.-G.; *Shi, Q., "Experimental and Theoretical Study of the Reactions between Cerium Oxide Cluster Anions and Carbon Monoxide: Size-Dependent Reactivity of Ce_nO_2n+1⁻ (n = 1-21)" J. Phys. Chem. C. 2011, 115, 13329-13337. 

(41) Wang, Z.-C.; Wu, X.-N.; Zhao, Y.-X.; Ma, J.-B.; *Ding, X.-L.; He, S.-G., "C-H Activation on Aluminum-Vanadium Bimetallic Oxide Cluster Anions" Chem. Eur. J. 2011, 17, 3449-3457. 

(40) Xu, B.; Zhao, Y.-X.; Li, X.-N.; Ding, X.-L.; *He, S.-G., "Experimental and Theoretical Study of Hydrogen Atom Abstraction from n-Butane by Lanthanum Oxide Cluster Anions" J. Phys. Chem. A. 2011, 115, 10245-10250. 

(39) Ma, Y.-P.; Zhao, Y.-X.; Li, Z.-Y.; *Ding, X.-L.; *He, S.-G., "Classification of V_xO_y^q Clusters by ∆ = 2y+q-5x" Chinese J. Chem. Phys. 2011, 24, 596-596. 

(38) Wu, X.-N.; Xu, B.; Ma, J.-B.; *He, S.-G., "Collision-Induced Characterization of adsorption of small molecules over atomic clusters through collisions with helium beam" SCIENTIA SINICA Chimica 2011, 41, 1379-1386 (In Chinese).

(37) Xue, L.; Li, G.-P.; Liu, Q.; Wang, H.-H.; Liu, C.; Ding, X.-L.; *He, S.-G.; *Jiang, H., "Ratiometric Fluorescent Sensor Based on Inhibition of Resonance for Detection of Cadmium in Aqueous Solution and Living Cells" Inorg. Chem. 2011, 50, 3680-3690.

(36) Wu, X.-N.; Ma, J.-B.; Xu, B.; Zhao, Y.-X.; Ding, X.-L.; *He, S.-G., "Collision-Induced Dissociation and Density Functional Theory Studies of CO Adsorption over Zirconium Oxide Cluster Ions: Oxidative and Nonoxidative Adsorption" J. Phys. Chem. A 2011, 115, 5238-5246. 

(35) Ke, D.-M.; *Zhan, C.-L.; Xu, S.-P.; Ding, X.-L.; Peng, A.-D.; Sun, J.; He, S.-G.; *Li, A. D. Q.; *Yao, J.-N., "Self-Assembled Hollow Nanospheres Strongly Enhance Photoluminescence" J. Am. Chem. Soc. 2011, 133, 11022-11025. 

 

2010年发表论文

(34) Ding, X.-L.; Zhao, Y.-X.; Wu, X.-N.; Wang, Z.-C.; Ma, J.-B.; *He, S.-G., "Hydrogen-Atom Abstraction from Methane by Stoichiometric Vanadium-Silicon Heteronuclear Oxide Cluster Cations" Chem. Eur. J. 2010, 16, 11463-11470. 

(33) Wu, X.-N.; Zhao, Y.-X.; Xue, W.; Wang, Z.-C.; *He, S.-G.; *Ding, X.-L., "Active sites of stoichiometric cerium oxide cations (Ce_mO_2m⁺) probed by reactions with carbon monoxide and small hydrocarbon molecules" Phys. Chem. Chem. Phys. 2010, 12, 3984-3997. 

(32) Zhao, Y.-X.; Wu, X.-N.; Wang, Z.-C.; *He, S.-G.; *Ding, X.-L., "Hydrogen-atom abstraction from methane by stoichiometric early transition metal oxide cluster cations" Chem. Commun. 2010, 46, 1736-1738. 

(31) Ma, J.-B.; Wu, X.-N.; Zhao, Y.-X.; Ding, X.-L.; *He, S.-G., "Characterization of Mononuclear Oxygen-Centered Radical (O^-o) in Zr₂O₈⁻ Cluster" J. Phys. Chem. A 2010, 114, 10024-10027. 

(30) Ma, J.-B.; Wu, X.-N.; Zhao, X.-X.; Ding, X.-L.; *He, S.-G., "Methane activation by V₃PO₁₀^·+ and V₄O₁₀^·+ clusters: A comparative study" Phys. Chem. Chem. Phys. 2010, 12, 12223-12228.

(29) Zhao, Y.-X.; Ding, X.-L.; Ma, Y.-P.; Wang, Z.-C.; *He, S.-G., "Transition metal oxide clusters with character of oxygen-centered radical: a DFT study" Theor. Chem. Acc. 2010, 127, 449-465. 

(28) Wang, Z.-C.; Wu, X.-N.; Zhao, Y.-X.; Ma, J.-B.; Ding, X.-L.; *He, S.-G., "Room-temperature methane activation by a bimetallic oxide cluster AlVO₄⁺" Chem. Phys. Lett. 2010, 489, 25-29. 

(27) Ma, Y.-P.; Ding, X.-L.; Zhao, Y.-X.; *He, S.-G., "A Theoretical Study on the Mechanism of C₂H₄ Oxidation over a Neutral V₃O₈ Cluster" ChemPhysChem 2010, 11, 1718-1725.

(26) Ding, X.-L.; Xue, W.; Ma, Y.-P.; Zhao, Y.-X.; Wu, X.-N.; *He, S.-G., "Theoretical Investigation of the Selective Oxidation of Methanol to Formaldehyde on Vanadium Oxide Species Supported on Silica: Umbrella Model" J. Phys. Chem. C 2010, 114, 3161-3169.

(25) Zhao, Y.-X.; Wu, X.-N.; Ma, J.-B.; *He, S.-G.; *Ding, X.-L., "Experimental and Theoretical Study of the Reactions between Vanadium-Silicon Heteronuclear Oxide Cluster Anions with n-Butane" J. Phys. Chem. C 2010, 114, 12271-12279.

(24) Ma, J.-B.; Wu, X.-N.; Zhao, Y.-X.; *He, S.-G.; *Ding, X.-L., "Experimental and Theoretical Studies of the Reactions between Vanadium Oxide Cluster Anions and Small Hydrocarbon Molecules" Acta Physico-Chimica Sinica 2010, 26, 1761-1767 (Invited). 

(23) Ma, J.-B.; Wu, X.-N.; Zhao, Y.-X.; Ding, X.-L.; *He, S.-G., "Experimental and Theoretical Study of Hydrogen Atom Abstraction from C₂H₆ and C₄H₁₀ by Zirconium Oxide Clusters Anions" Chinese J. Chem. Phys. 2010, 23, 133-137. 

(22) Wang, Z.-C.; Ma, Y.-P.; Zhao, Y.-X.; Ding, X.-L.; He, S.-G., "Nearly Monodispersed Perylene Nanotablets: Easy Fabrication and Unique Optical Properties" Inec: 2010 3^rd International Nanoelectronics Conference 2010, 1-2, 425-426. 

 

2009年发表论文

(21) Zhang, Y.-Q.; *Chen, P.-L.; Ma, Y.-P.; He, S.-G.; *Liu, M.-H., "Acidification and Assembly of Porphyrin at an Interface: Counterion Matching Selectivity and Supramolecular Chirality" Acs Applied Materials & Interfaces 2009, 1, 2036-2043. 

(20) Yin, S.; Xue, W.; Ding, X.-L.; Wang, W.-G.; *He, S.-G.; *Ge, M.-F., "Formation distribution and structures of oxygen-rich iron and cobalt oxide clusters" Int. J. Mass Spectrom. 2009, 281, 72-78. 

(19) Yin, S.; *He, S.-G.; *Ge, M.-F., "Reaction between sulfur dioxide and iron oxide cationic clusters" Chinese Sci. Bull. 2009, 54, 4017-4020. 

(18) Xue, W.; Yin, S.; Ding, X.-L.; *He, S.-G., Ge M-F*, "Ground State Structures of Fe₂O_4-6⁺ Clusters Probed by Reactions with N₂" J. Phys. Chem. A 2009, 113, 5302-5309. 

(17) Wu, X.-N.; Zhao, Y.-X.; *He, S.-G.; *Ding, X.-L., "Experimental and Theoretical Study of Hydrogen Atom Abstraction from Ethylene by Stoichiometric Zirconium Oxide Clusters" Chinese J. Chem. Phys. 2009, 22, 635-641. 

(16) Wang, Z.-C.; Ding, X.-L.; Ma, Y.-P.; Cao, H.; Wu, X.-N.; Zhao, Y.-X.; *He, S.-G., "Theoretical study of partial oxidation of ethylene by vanadium trioxide cluster cation" Chinese Sci. Bull. 2009, 54, 2814-2821.

(15) Ma, Y.-P.; *He, S.-G.; Ding, X.-L.; Wang, Z.-C.; Xue, W.; *Shi, Q., "Theoretical study of intermolecular interactions in meso-tetraphenylporphyrin diacid dimer (H₄TPPCl₂)₂" Phys. Chem. Chem. Phys. 2009, 11, 2543-2552. 

(14) Hu, H.-Y.; Xue, W.; Hu, Z.-Q.; Xiang, J.-F.; *Chen, C.-F.; *He, S.-G., "Probing the Dynamic Environment-Associated Conformational Conversion from Secondary to Supersecondary Structures in Oligo(phenanthroline dicarboxamide)s" J. Org. Chem. 2009, 74, 4949-4957. 

(13) He, S.-G.; Sunahori, F.-X.; Yang, J.; *Clouthier, D.-J., "Heavy atom nitroxyl radicals. II: Spectroscopic detection of H₂As=O the prototypical arsenyl free radical" J. Chem. Phys. 2009, 131, 114311.

(12) Dong, F.; Heinbuch, S.; Xie, Y.; *Bernstein, E.-R.; Rocca, J.-J.; Wang, Z.-C.; Ding, X.-L.; *He, S.-G., "C=C Bond Cleavage on Neutral VO₃(V₂O₅)_n Clusters" J. Am. Chem. Soc. 2009, 131, 1057-1066. 

(11) Ding, X.-L.; Xue, W.; Ma, Y.-P.; Wang, Z.-C.; *He, S.-G., "Density functional study on cage and noncage (Fe₂O₃)_n clusters" J. Chem. Phys. 2009, 130, 014303.

 

2008年发表论文

(10) Xue, W.; Wang, Z.-C.; *He, S.-G.; Xie, Y.; *Bernstein, E. R., "Experimental and Theoretical Study of the Reactions between Small Neutral Iron Oxide Clusters and Carbon Monoxide" J. Am. Chem. Soc. 2008, 130, 15879-15888. 

(9) Dong, F.; Heinbuch, S.; Xie, Y.; Rocca, J.-J.; *Bernstein, E.-R.; Wang, Z.-C.; Deng, K.; *He, S.-G., "Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane ethylene and acetylene" J. Am. Chem. Soc. 2008, 130, 1932-1943. 

(8) Yin, S.; Ma, Y.-P.; Du, L.; *He, S.-G.; *Ge, M.-F., "Experimental and theoretical studies of the reaction between cationic vanadium oxide clusters and acetylene" Chinese Sci. Bull. 2008, 53, 3829-3838. 

(7) Xie, Y.; He, S.-G.; Dong, F.; *Bernstein, E.-R., "Reaction of carbon monoxide and hydrogen on neutral Nb₈ clusters in the gas phase" J. Chem. Phys. 2008, 128, 044306.

(6) Wang, Z.-C.; Xue, W.; Ma, Y.-P.; Ding, X.-L.; *He, S.-G.; Dong, F.; Heinbuch, S.; Rocca, J.-J.; Bernstein, E.-R., "Partial oxidation of propylene catalyzed by VO₃ clusters: A density functional theory study" J. Phys. Chem. A 2008, 112, 5984-5993. 

(5) Wang, Z.-C.; Xiao, W.-C.; Ding, X.-L.; Ma, Y.-P.; Xue, W.; *He, S.-G., "Multicolor emission from large-area porous thin films constructed of nanowires of small organic molecules" Nanotechnology 2008, 19. 

(4) Ma, Y.-P.; Xue, W.; Wang, Z.-C.; Ge, M.-F.; *He, S.-G., "Acetylene cyclotrimerization catalyzed by TiO₂ and VO₂ in the gas phase: A DFT study" J. Phys. Chem. A 2008, 112, 3731-3741. 

(3) He, S.-G.; Xie, Y.; Dong, F.; Heinbuch, S.; Jakubikova, E.; Rocca, J.-J.; *Bernstein, E.-R., "Reactions of Sulfur Dioxide with Neutral Vanadium Oxide Clusters in the Gas Phase. II. Experimental Study Employing Single-Photon Ionization" J. Phys. Chem. A 2008, 112, 11067-11077.

(2) *He, S.-G.; Clouthier, D.-J., "RT₃: A Windows program for the Renner-Teller analysis of ²Π states of triatomic molecules" Comp. Phys. Commun. 2008, 178, 676-684. 

(1) *Ge, M.-F.; Du, L.; Ma, Y.-P.; He, S.-G., "Ab initio and DFT study of the structural properties and thermochemistry of CH₃SO₂OONO₂ atmospheric molecule and CH₃SO₂OO radical" Chinese J. Chem. 2008, 26, 998-1004.