成果简介
1、CO2活化
Jiang L-X, Zhao C,Li X-N*, Chen H*,He S-G*. "Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions", Angew. Chem. Int. Ed, 2017, 56, 4187-4191.
2、纳米尺寸团簇活性
Zhang M-Q, Zhao Y-X*, Liu Q-Y, Li X-N, He S-G*. "Does Each Atom Count in the Reactivity of Vanadia Nanoclusters?", J. Am. Chem. Soc. 2017, 139, 342-347.
3、CH4活化
Li Z-Y, Li H-F, Zhao Y-X*, He S-G*. "Gold (III) Mediated Activation and Transformation of Methane on Au1-doped Vanadium Oxide Cluster Cations AuV2O6+", J. Am. Chem. Soc.2016, 138, 9437-9443.
Li Y-K, Yuan Z, Zhao Y-X*, Zhao C, Liu Q-Y, Chen H*, He S-G*. "Thermal Methane Conversion to Syngas Mediated by Rh1‑Doped Aluminum Oxide Cluster Cations RhAl3O4+", J. Am. Chem. Soc.2016, 138, 12854-12860.
Liu Q-Y, Ma J-B*, Li Z-Y, Zhao C, Ning C-G, Chen H*, He S-G*. "Activation of Methane Promoted by Adsorption of CO on Mo2C2- Cluster Anions",Angew. Chem. Int. Ed.2016, 55, 5760.
4、CO氧化
Li X-N, Zhang H-M,Yuan Z, He S-G*. "A Nine-Atom Rhodium-Aluminum Oxide Cluster Oxidizes Five Carbon Monoxide Molecules", Nat. Commun, 2016, 7, 11404.